Bis(4-aminobenzenesulfonato)triaquabis(1,10-phenanthroline)neodymium(III) nitrate tetrahydrate
نویسندگان
چکیده
The title complex, [Nd(C(6)H(6)NO(3)S)(2)(C(12)H(8)N(2))(2)(H(2)O)(3)]NO(3)·4H(2)O, comprises a mononuclear cation, an NO(3) (-) anion and two uncoordinated water mol-ecules; the Nd(III) cation, one coordinated water mol-ecule, and the NO(3) (-) anion each lie on a twofold axis of symmetry. The Nd(III) ion exhibits an NdN(4)O(5) coordination environment comprising two O atoms of two monodentate 4-amino-benzene-sulfonato ligands, four N atoms of the bidentate 1,10-phenanthroline ligands, and three water-O atoms. The coordination geometry is based on a tricapped triangular-prismatic arrangement. The components are consolidated into a three-dimensional network via O-H⋯O, O-H⋯N and N-H⋯O hydrogen-bonding inter-actions.
منابع مشابه
Bis(2,6-dihydroxybenzoato-κ2 O 1,O 1′)(nitrato-κ2 O,O′)bis(1,10-phenanthroline-κ2 N,N′)neodymium(III)
In the mononuclear title complex, [Nd(C(7)H(5)O(4))(2)(NO(3))(C(12)H(8)N(2))(2)], the Nd(III) atom is in a distorted bicapped square-anti-prismatic geometry formed by four N atoms from two chelating 1,10-phenanthroline (phen) ligands, four O atoms from two 2,6-dihy-droxy-benzoate (DHB) ligands and two O atoms from a nitrate anion. π-π stacking inter-actions between the phen and DHB ligands of a...
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In the title complex, [La(2)(C(10)H(10)NO(3))(2)(NO(3))(4)(C(12)H(8)N(2))(4)], each La(III) ion is ten-coordinated by four N atoms from two bidentate 1,10-phenanthroline ligands and by six O atoms, two from the N-acetyl-N-phenyl-glycinate ligands and four from two nitrate anions. Two La(III) cations, which exhibit a distorted bicapped square-anti-prismatic coordination, are bridged by two N-ace...
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The reaction of cadmium nitrate and sodium nitrite in the presence of 1,10-phenanthroline yields the mixed nitrate-nitrite title complex, [Cd(NO(2))(1.75)(NO(3))(0.25)(C(12)H(8)N(2))(2)]. The metal ion is bis-chelated by two N-heterocycles as well as by the nitrate/nitrite ions in a distorted dodeca-hedral CdN(4)O(4) coordination environment. One nitrite group is ordered; the other is disordere...
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The title complex, [Pr(C(7)H(5)O(3))(2)(NO(3))(C(12)H(8)N(2))]·2C(12)H(8)N(2), has a polymeric chain structure, with two uncoordinated 1,10-phenanthroline mol-ecules in the lattice. The Pr(III) centre has a monocapped square-anti-prismatic coordination geometry, comprised of two N atoms from one chelating 1,10-phenanthroline ligand, four carboxyl-ate O atoms from four 4-hy-droxy-benzoate anions...
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